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Compound - 2R3R-hexanediol

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(2R,3R)-2,3-Hexanediol Formula:  C6H14O2  CAS#:  617-30-1  MW:  118.17  [MS]  [ NMR ]  [ Kovats ]  [Behavioural function]  [Chemdraw]

Dots surface:

Reference(s) for synthesis of (2R,3R)-2,3-Hexanediol Balsells, R.E., and Frasca, A.R. 1982. Photochemical reaction of alcohols-I: irradiation of aliphatic alcohols. Tetrahedron. 38:245-255.   Bonini, C., Federici, C., Rossi, L., and Righi, G. 1995. C-1 Reactivity of 2,3-epoxy alcohols via oxirane opening with metal halides: Applications and synthesis of naturally occurring 2,3-octanediol, muricatacin, 3-octanol, and 4-dodecanolide. J. Org. Chem. 60:4803-4812.   Bonini, C., Giuliano, C., Righi, G., and Rossi, L. 1992. A new unusual C-1 substitution of 2,3 epoxy alcohols with liI: regio and stereoselective obtaining of 1-iodo 2,3 diols and 2,3-diols. Tetrahedron Lett. 33:7429-7432.   Gagnaire, D., and Monzeglio, P. 1964. C. R. Hebd. Seances Acad. Sci. 259:1128-1131.   Heathcock, C.H., Kiyooka, S.-I., Blumenkopf, T.A. 1984. Acyclic stereoselection. 22. Diastereofacial selectivity in the Lewis acid mediated reactions of allylsilanes with chiral aldehydes and enones. J. Org. Chem. 49:4214-4223.   Schroeder, F., Fettkoether, R., Noldt, U., Dettner, K., Koenig, W.A., and Francke, W. 1994. Synthesis of (3R)-3-Hydroxy-2-hexanone, (2R,3R)-2,3-Hexanediol and (2S,3R)-2,3-Hexanediol, the male sex pheromone of Hylotrupes bajulus and Pyrrhidium sanguineum (Cerambycidae). Liebigs Ann. Chem. 12:1211-1218.   Stojanovic, A., Renaud, P., and Schenk, K. 1998. Stereoselective reactions of phthalimido-substituted radicals derived from (±)-threonine: a comparison with reactions of N-phthaloyliminium ions. Helv. Chim. Acta. 81:268-284.